Atoms are made up of 3 types of particles electrons ,
protons
and neutrons .
These particles have different properties. Electrons are tiny, very
light particles that have a negative electrical charge (-). Protons
are much larger and heavier than electrons and have the opposite charge, protons
have a positive charge. Neutrons
are large and heavy like protons, however neutrons have no electrical charge.
Each atom is made up of a combination of these particles. Let's look at
one type of atom:
A neutron walked into a bar and
asked how much for a drink.
The bartender replied,
"for you, no charge."
-Jaime - Internet Chemistry Jokes
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The atom above, made up of one proton and one electron, is called hydrogen (the
abbreviation for hydrogen is H). The proton and electron stay together
because just like two magnets, the opposite electrical charges attract each
other. What keeps the two from crashing into each other? The
particles in an atom are not still. The electron is constantly spinning
around the center of the atom (called the nucleus). The centrigugal force
of the spinning electron keeps the two particles from coming into contact with
each other much as the earth's rotation keeps it from plunging into the sun.
Taking this into consideration, an atom of hydrogen would look like this:
A Hydrogen Atom
Keep in mind that atoms
are extremely small. One hydrogen atom, for example, is approximately 5 x
10-8 mm in diameter. To put that in perspective, this dash - is
approximately 1 mm in length, therefore it would take almost 20 million hydrogen
atoms to make a line as long as the dash. In the sub-atomic world, things
often behave a bit strangely. First of all, the electron actually spins
very far from the nucleus. If we were to draw the hydrogen atom above to
scale, so that the proton were the size depicted above, the electron would
actually be spinning approximately 0.5 km (or about a quarter of a mile) away
from the nucleus. In other words, if the proton was the size depicted
above, the whole atom would be about the size of Giants Stadium. Another
peculiarity of this tiny world is the particles themselves. Protons and
neutrons behave like small particles, sort of like tiny billiard balls.
The electron however, has some of the properties of a wave. In other
words, the electron is more similar to a beam of light than it is to a billiard
ball. Thus to represent it as a small particle spinning around a nucleus
is slightly misleading. In actuality, the electron is a wave that
surrounds the nucleus of an atom like a cloud. While this is difficult to
imagine, the figure below may help you picture what this might look like:
Hydrogen: a proton surrounded by an electron cloud

While you should keep in mind that electrons actually form clouds around
their nucleii, we will continue to represent the electron as a spinning particle
to keep things simple.
In an electrically neutral atom, the
positively charged protons are always balanced by an equal number of negatively
charged electrons. As we have seen, hydrogen is the simplest atom with
only one proton and one electron. Helium is the 2nd simplest atom.
It has two protons in its nucleus and two electrons spinning around the nucleus.
With helium though, we have to introduce another particle. Because the 2
protons in the nucleus have the same charge on them, they would tend to repel
each other, and the nucleus would fall apart. To keep the nucleus from
pushing apart, helium has two neutrons in its nucleus. Neutrons have no
electrical charge on them and act as a sort of nuclear glue, holding the
protons, and thus the nucleus, together.
A Helium Atom
As you can see, helium is larger than hydrogen. As you add electrons,
protons and neutrons, the size of the atom increases. We can measure an
atom's size in two ways: using the atomic number (Z) or using the atomic mass
(A, also known as the mass number). The atomic number describes the number
of protons in an atom. For hydrogen the atomic number, Z, is equal to 1.
For helium Z = 2. Since the number of protons equals the number of
electrons in the neutral atom, Z also tells you the number of electrons in the
atom. The atomic mass tells you the number of protons plus neutrons
in an atom. Therefore, the atomic mass, A, of hydrogen is 1. For
helium A = 4.
Ions and Isotopes
So far we have only talked about
electrically neutral atoms, atoms with no positive or negative charge on them.
Atoms, however, can have electrical charges. Some atoms can either gain or
lose electrons (the number of protons never changes in an atom). If an
atom gains electrons, the atom becomes negatively charged. If the atom
loses electrons, the atom becomes positively charged (because the number of
positively charged protons will exceed the number of electrons). An atom
that carries an electrical charge is called an ion. Listed below
are three forms of hydrogen; 2 ions and the electrically neutral form.
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| H+ : a positively charged
hydrogen ion |
H : the hydrogen atom |
H- : a negatively charged
hydrogen ion |
Neither the number of protons nor
neutrons changes in any of these ions, therefore both the atomic number and the
atomic mass remain the same. While the number of protons for a given atom
never changes, the number of neutrons can change. Two atoms with different
numbers of neutrons are called isotopes. For example, an isotope of
hydrogen exists in which the atom contains 1 neutron (commonly called
deuterium). Since the atomic mass is the number of protons plus neutrons,
two isotopes of an element will have different atomic masses (however the atomic
number, Z, will remain the same).
Two isotopes of hydrogen
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Hydrogen
Atomic Mass = 1
Atomic Number = 1 |
Deuterium
Atomic Mass = 2
Atomic Number = 1 |
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