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My
parents, Charles Brovarnik and Pearl Gorinstein, were born in Zhitomir
in the Ukraine and came to London in 1908 as part of the vast Jewish immigration
in the early part of this century. They were married in London. In 1909
my sister, Ann, was born. I arrived on May 22, 1912. In June 1914 my father
decided to join his mother and father and other members of his family
in Chicago, much to the dismay of my mother, whose own family largely
remained in England.
My grandfather's
name had been anglicized to Brown, and that became our name. In the United
States, my two sisters, Sophie and Riva, were born in 1916 and 1918. My
father had been trained as a cabinet maker, doing delicate inlaid work.
However, he found little market for his skills in the U.S. and turned
to carpentry. The Depression of 1920 persuaded him to go into business
and he opened a small hardware store in Chicago at 18th and State Street,
largely a black neighborhood. We lived in an apartment above the store
and I attended the Haven School at Wabash and 16th Street with predominantly
black classmates. I did well in school and was advanced several times,
graduating at 12. Indeed, I was offered, but refused, further advancement
since I did not want to be in the same class with my sister, Ann. On graduation,
I went to Englewood High School on the South Side of Chicago.
Unfortunately, my father became ill of some sort of infection and died
in 1926. I left school to work in our store. I am afraid that I was not
really interested in the business and spent most of my time reading. My
mother finally decided that she would attend the store and I should go
back to school. Accordingly, I reentered Englewood in February 1929 and
graduated in 1930. At Englewood I ran the humor column of the school paper
and won a national prize. I never recovered. We sold the store at that
time. I had no hope of going on to college. However, this was the beginning
of the Depression and I could find no permanent job. Studying appealed
to me much more than the odd jobs I could find. I decided to go to college.
I entered college intending to major in electrical engineering. I had
heard that one could make a good living in that area.
However, I took chemistry and became fascinated with that subject, and
remained with chemistry thereafter. I had just completed one semester
at Crane Junior College when it was announced in 1933 that the school
was to be closed for lack of funds. I then went to night school at the
Lewis Institute, taking one or two courses, financing myself by working
as a parttime shoe clerk. I then heard that one of the instructors at
Crane, Dr.Nicholas Cheronis, had opened his laboratory to several students,
so that they could continue their studies on their own. I went there and
grew to know and love a fellow student, Sarah Baylen. Sarah had been the
brightest student in chemisy at Crane prior to my arrival. She has described
("Remembering HCB") how she initially "hated my guts." But since she could
not beat me, she later decided to join me, to my everlasting delight.
In 1934 Wright Junior College opened its doors. We went there and nine
of us graduated in 1935 as the first graduating class. In my yearbook
Sarah predicted that I would be a Nobel Laureate! I had been advised to
take the competitive examination for a scholarship at the University of
Chicago. I did so. To my astonishment, little of the examination was devoted
to the chemistry, physics, and mathematics that had constituted the major
portion of my studies. Instead, the examination emphasized general subjects:
history, art, music, literature, etc. - subjects I had never studied formally.
I did the best I could and was pleasantly surprised when I received a
half scholarship. I entered the University of Chicago in the Fall of 1935,
accompanied by my girlfriend, Sarah. This was the time when the President
of the University, Robert Maynard Hutchins, was arguing for the principle
that students should be permitted to proceed as rapidly as possible. Indeed,
at that time it cost no more to take ten courses than it did the usual
three. I did so, and completed my junior and senior year in three quarters,
receiving the B.S. in 1936. I did not apply for graduate work. I wanted
to find a job and marry my girlfriend.
However, a famous organic chemist, Julius Stieglitz - then Emeritus, but
still teaching - called me into his office and urged me to reconsider
my decision. He predicted a favorable future as a research chemist. I
discussed the matter with Sarah and she agreed that marriage could wait.
Accordingly, I began graduate work. On my graduation, Sarah presented
me with a gift - a copy of Alfred Stock's book, The Hydrides of Boron
and Silicon. This book interested me in the hydrides of boron and I undertook
to study with Professor H.I. Schlesinger, then active in that area of
research. Sarah and I were married "secretly" on February 6, 1937. We
were such innocents that we did not realize that marriages are published
in the daily newspapers. Consequently, our marriage was a secret for the
weekend! Once the news got out, I had to begin supporting her. But my
income as a graduate assistant was only $400 per year, out of which had
to come $300 for tuition. But Sarah obtained a position at Billings Hospital
in Medical Chemistry and kept us solvent. I received my Ph.D. in 1938.
Unfortunately (perhaps fortunately), I could not find an industrial position.
Professor M. S. Kharasch then offered me a position as a postdoctorate
at a stipend of $1600 and my academic career was initiated. The following
year Professor Schlesinger invited me to become his research assistant
with the rank of Instructor, replacing Anton B. Burg, who was moving on
to the University of Southern California. Consequently, I am an unusual
example of a chemist who ended up in academic work because he could not
find an industrial position. At that time one did not achieve tenure until
after ten years. I had seen a number of individuals who had remained at
Chicago as Instructors for nine years without tenure and then had to find
another position under severe pressure. I decided to avoid this situation.
Accordingly, after four years I asked Professor Schlesinger for a decision
as to my future in the Department. When he came back with the word that
there was no future, I undertook to find another position.
Fortunately, Morris Kharasch had a good friend, Neil Gordon, who had just
gone as Department Head to Wayne University in Detroit. (Neil Gordon,
the originator of the Gordon Research Conferences, had given Morris Kharasch
his first position at the University of Maryland back in 1920.) Neil Gordon
was persuaded to give me a position at Wayne as Assistant Professor, preserving
my academic career. I became Associate Professor in 1946, and was invited
to Purdue in 1947 by the Head of the Chemistry Department, Henry B. Hass,
as Professor of Inorganic Chemistry. In 1959 I became Wetherill Distinguished
Professor and in 1960 Wetherill Research Professor. I became Emeritus
in 1978, but continue to work with a large group of postdoctorates. Originally
my research covered physical, organic and inorganic chemistry and I took
students in all three areas. However, as the Department became more organized
into divisions, it became necessary to make a choice, and I elected to
work primarly with coworkers in organic chemistry. In addition to my research
program in the borane-organoborane area, described in my Nobel Lecture,
my research program has involved the study of steric effects, the development
of quantitative methods to determine steric strains, the examination of
the chemical effects of steric strains, the non-classical ion problem,
the basic properties of aromatic hydrocarbons, a quantitative theory of
aromatic substitution, and the development of a set of electrophilic substitution
constants, sigma+, which correlate aromatic substitution data and a wide
variety of electrophilic reactions.
Recognitions:
Professor Brown
was the Harrison Howe Lecturer in 1953, the Centenary Lecturer of The
Chemical Society (London) in 1955, and the Baker Lecturer in 1968. He
was elected to the National Academy of Sciences in 1957, the American
Academy of Arts and Sciences in 1966, received an honorary Doctorate of
Science degree from the University of Chicago in 1968 and was elected
Honorary Fellow of The Chemical Society and Foreign Member of the Indian
National Academy of Sciences in 1978. Finally, he is the recipient of
the Nichols Medal for 1959, the ACS Award for Creative Research in Synthetic
Organic Chemistry for 1960, the Linus Pauling Medal for 1968, the National
Medal of Science for 1969, the Roger Adams Medal for 1971, the Charles
Frederick Chandler Medal for 1973, the Madison Marshall Award for 1975,
the CCNY Scientific Achievement Award Medal for 1976, the Allied Award
for 1978, the Ingold Memorial Lecturer and Medal for 1978, the Elliott
Cresson Medal for 1978, and the Nobel Prize for 1979.
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