Themes > Science > Chemistry > General Chemistry > Atomic Structure > Electronic Structures of Atoms > Electronic Structures of Atoms > Quantum-Mechanical Model


Erwin Schrödinger, in developing a quantum-mechanical model for the atom, began with a classical equation for the properties of waves. He modified this equation to take into account the mass of a particle and the de Broglie relationship between mass and wavelength. The important consequences of the quantum-mechanical view of atoms are the following:-

  1. The energy of electrons in atoms is quantised.
  2. The number of possible energy levels for electrons in atoms of different elements is a direct consequence of wave-like properties of electrons.
  3. The position and momentum of an electron cannot both be determined simultaneously.
  4. The region in space around the nucleus in which an electron is most probably located is what can be predicted for each electron in an atom. Electrons of different energies are likely to be found in different regions. The region in which an electron with a specific energy will most probably be located is called an atomic orbital.


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