| Themes > Science > Chemistry > Inorganic Chemistry > Gas Laws > More Gas Laws > Kinetic Molecular Theory of Gases |
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As expected, real gases do not conform to these assumptions, but they are accurate in explaining ideal gas behavior. The average kinetic energy of a gas can be determined if given the temperature. The equation used is (KE)avg = 1.5 RT, where R is equal to 8.3145 J/K mol (which is also equal to .08026 L atm/K mol, but different units). Temperature must also be expressed in Kelvin. Temperature can also be used to determine the root mean square velocity. Symbolized as urms, root mean square velocity is equal to (sq. root)(3RT)/M. In this equation R is equal to 8.3145 J/K mol, T must be Kelvins, and M is the mass of a mole of gas particles in kilograms. The root mean square velocity is in the units m/s. Although urms for oxygen gas at STP is about 500 m/s, the majority of the O2 molecules are not actually going that fast. Instead, the actual distribution of the velocities is shown in the graph below. |
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