Themes > Science > Chemistry > Inorganic Chemistry > Chemical Reaction , Chemical Formulas , Chemical Equation > Chemical Reaction > Chemical Kinetics > Order of Molecularity


Some reactions occur in a single step. The reaction in which a chlorine atom is transferred from ClNO2 to NO to form NO2 and ClNO is a good example of a one-step reaction.

ClNO2(g) + NO(g) <-----> NO2(g) + ClNO(g)

Other reactions occur by a series of individual steps. N2O5, for example, decomposes to NO2 and O2 by a three-step mechanism.

Step 1: N2O5 <----> NO2 + NO3
Step 2: NO2 + NO3 <----> NO2 + NO + O2
Step 3: NO + NO3 <----> 2 NO2

The steps in a reaction are classified in terms of molecularity, which describes the number of molecules consumed. When a single molecule is consumed, the step is called unimolecular. When two molecules are consumed, it is bimolecular.


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