In general, if charges are in the presence of an electric field ,
they will acquire a potential energy. Recall that if the force is conservative,
then, as discussed in Section 3.7, force can be replaced by potential
energy, denoted by .
In the case of the Coulomb force, a direct demonstration can be made to
show that it is a conservative force. Since force is proportional to the
electric field, it follows that the (stationary) electric field can be
expressed as the gradient of the ``electrostatic potential'',
denoted by .
The force on a charge
due to an electric field
is given by
 |
(7.9) |
and hence
 |
(7.10) |
In other words, the potential energy
is proportional to the electrostatic potential .
Consider the two points
with electrostatic potential ;
the electric field is then given by
The
field is the negative of the gradient of the electrostatic
potential so that it points from a higher value of
to a lower value, in keeping with the force pointing in the direction of
decreasing potential.
Figure
7.7: Electric Field from
Electrostatic Potential
 |
Since
,
the dimensions of the electrostatic potential is given by
.
The units for
in the SI system is called Volts (V) and is given by
 |
(7.13) |
In terms of volts, we have a simpler
expression for the units of electric field. Recall that
.
In term of volts, we have
![\begin{displaymath}[{\bf E}]=\mbox{\rm {volts per meter}}\equiv VM^{-1}
\end{displaymath}](img887.png) |
(7.14) |
Note that the electrostatic potential
is not a vector; rather at every point in space
only a single number
completely specifies the .
A field such as
is called a scalar field. Clearly it is much easier to analyze a
scalar field such as
compared to a vector field like ,
and this is one of the main reasons for working with potentials. The
contours of constant
lines are plotted in Figure 7.7. Since the electrostatic force is
conservative, the energy of a particle at some point is independent of the
path it took to get there. As shown in Figure 7.7, the difference in the
energy of a charged particle is the same whether it takes path 1 or path 2
in going from the surface
to the surface .
Figure 7.8 shows the lines of equipotential in three dimensions. The lines
with a high value of
are analogous to a point of high elevation for a body moving under the
influence of gravity. Just as in gravity a mass
can gain potential energy in going from a lower to a higher height, a positively
charged particle also gains potential energy in moving from a point
with a lower to a point with a higher electrostatic
potential ;
however, and this is what makes electromagnetism so different from
gravity, negatively charged particle loses energy in moving
from a point with a lower value of
to one with a higher value.
Figure
7.8: Equipotential Surface in
Three Dimensions
 |
A charged particle will take the shortest path in going from a
point at a higher to a point at a lower potential. In effect, the charge
moves under the force created by the electric field derived from the
potential .
The direction of the electric field at some point on a contour points in
the direction of the shortest distance to close-by contour points, as
shown in Figure 7.7. The magnitude of
is determined by the steepness of the contours. What is the rationale for
separating out the electrostatic potential from the potential energy of
two charges? In contrast to say gravity, for which mass is always a
positive quantity, electric charge can either be negative or positive.
Hence, by separating off the electrostatic potential
from potential ,
we can study the field
generated by a given charge, and then analyze how it affects other
charges. Suppose
is generated by a positive charge; a negative charge will move towards increasing
values of
whereas a positive charge will move towards decreasing values of ,
as shown in Figure 7.9. A potential
that looks like a ``mountain'' to a positively charged particle
looks like a ``crater'' to a negatively charged particle .
Figure
7.9: Positive and Negative Charge
Moving in the Same V-field
 |
Recall that the fundamental irreducible charge
in nature is the electron charge; by convention, the charge of the
electron is taken to be negative and is denoted by .
It is a natural constant, with the numerical value of
in the SI units given by
 |
(7.15) |
The value of the electron charge is extremely
small. In a typical light bulb, every second over
electron charges enter and leave the bulb's filament. Protons carry charge
equal to ,
and the proton seldom enters the processes that we will be interested in.
The electron charge is the basis of another unit for energy. The energy
gained by an electron, in moving from say a point with
volts in Figure 7.7 to a point with
volts, such that the electrostatic potential difference between the two
points is 1 volt is called an electron-volt, and is denoted by .
We consequently have
The electron-volt (eV) is the appropriate unit of energy to measure
energies involved in atomic, chemical and (molecular) biological
processes. The energy of a single molecule of air at room temperature is
about
eV.
Potential due to Point Charges
The potential energy of charges
and ,
separated by a distance ,
is given by Coulomb potential
 |
(7.19) |
From eq.(7.17) the electrostatic potential of
a point charge
is given by
Figure 7.10 shows the Coulomb potential.
Note the striking difference in the potentials due to a positive and
negative charge, with the positive charge giving a ``mountain'' and the
negative charge yielding a ``valley''.
Figure
7.10: Coulomb Potential for Positive and Negative Charge
 |
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