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As chemists, we are used to writing down chemical equations such as
2H2(g)+ O2(g) -> 2H2O(g). This reaction
doesn't include some important information however. We don't know if this
reaction gives off heat or requires heat from the surroundings, and we don't
know how much heat is generated.
In a thermochemical equation, we include the value of
DH, the change in enthalpy
for the reaction. For example, the above equation showing the combustion of
hydrogen would be written as
2H2(g)+ O2(g) -> 2H2O(g),
DH = -571.6 kJ
The sign and magnitude of the change in enthalpy tell us that this reaction
is exothermic and gives off a lot of heat. Some rules for writing thermochemical
equations are:
- The sign of DH indicates if the reaction is
exothermic (DH negative) or endothermic (DH positive)
- The coefficients in front of the species represent number of moles
- The phases of each reactant and product must be indicated: the
enthalpy of liquid water at 25oC is different from gaseous water at
the same temperature, for example
- The value of DH is computed with all reactants
and products at 25oC and 1 atm pressure unless otherwise indicated.
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