Themes > Science > Chemistry > Nuclear Chemistry > Radioactivity

     Certain elements spontaneously release energy and particles of matter 

     The number of neutrons vary in isotopes of the same element making little      difference chemically but the nuclear properties of the isotopes may vary a great      deal 

     Atoms with too many neutrons are unstable which may decay (a natural process      called radioactivity wherein the energy and particles emitted are nuclear radiation) 


Health issues


1)  this ionizing radiation can produce charged ions in materials that it strikes; can produce changes in living tissues (a potential health hazard) 
2)  extreme case = fatal, lower levels may cause changes in enough cells to induce sickness, cause a slightly increased incidence of cancer, or have developmental effects on unborn children 
3)  Radiation injuries:   hair loss and skin lesions, localized injuries similar to burns (normally to hands)
4)  Radiation sickness:  nausea, vomiting, diarrhea, malaise, hemorrhage and lowering of the body's resistance against disease and infection, if serious enough = death
5) Man-made radiation sources:  diagnostic X-rays, radiotherapy x-rays, television tubes, luminous watch dials, radioactive waste products

Units of measure:

  • roentgen (R) = a measurement of radiation in air/space only
  • REM  = measures radiation absorbed by a man or mammal, which produces a physiological effect  equivalent to that produced by the absorption of one roentgen of radiation.
  • mrem  =  millirem (1/1000 of a rem)
  • > 100 000 mrem = statistical identifiable effects 10 000 - 100 000 mrem = grey area < 10 000 mrem = no statistically identifiable effect  

Natural Radioactivity

a) release of alpha, beta, and gamma radiation along with spontaneous fission (breaking up of a nucleus into 2 large chunks with neutrons usually given off 

b) alpha particles charged particles similar to helium nuclei 1) can be stopped by a sheet of paper 2) problem is the possibility of alpha particles being inhaled or ingested with food or water 3) the protective layer of dead tissue found on skin is not present in lining of digestive, respiratory, and circulatory systems 

 alpha particles  -->   positively charged (+2)  particle with a mass of 4 (times that of hydrogen atom), similar to the nuclei of  helium ions

c) beta particles 

beta particles -->  negatively charged (-1) particle very similar to electron, travels somewhat faster

d) gamma radiation -X rays (from electron excitation) and gamma rays (from nuclear excitation) can only be stopped by several inches of lead or a foot of concrete  

gamma radiation  -->  as radiation, has no charge or mass but is energy and travels at speed of light, travels as photons (X-rays that come from electron excitation or gamma rays from nuclear excitation)

Radioactivity in bombs and power plants:

a) if enough mass (called the critical mass) of the isotope of uranium-235 is simply placed together it will produce an uncontrolled chain reaction in less than a millionth of a second. A chain reaction is when one atom fissions and the products cause the fission of additional atoms. If the chain reaction is uncontrolled, it is called an atomic bomb 
b) another danger from nuclear explosions are the neutrons - must dissipate energy as heat by using cadmium or boron absorbers (neutrons bounce off lead elastically with kinetic energy conserved) 
c) in order to artificially induce fission and harness the process to generate electricity in a nuclear power plant slow neutrons are directed at the uranium nucleus to split it and control rods are used to absorb some of the resulting increase in neutrons (there is never enough uranium in a reactor to reach critical mass)  

Decay schemes

alpha decay - radioactive nucleus that decays by giving off an alpha particle loses 2 protons and 2 neutrons.  The atomic number is reduced by 2 and the atomic mass by 4.

 radium-226   à    alpha   +     _____________   +   energy

beta decay - a radioactive nucleus that decays by giving off a beta particle loses an electron from the decay of a neutron into a proton, electron, anti-neutrino.  The atomic number is thus increased by 1.  The atomic mass stays the same.

thorium-234   à   beta   +    _____________  + energy

electron capture -  electron capture changes the nucleus by adding an electron from the innermost electron shell.  This electron from the electron cloud combines with a proton to form a neutron.  The atomic number is reduced by 1.  The atomic mass stays the same.

potassium-40   +   electron capture  à   ________________


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