| Themes > Science > Physics > Solid State Physics > Atomic Bonding and Crystal Structure > Crystal Structure and Crystal Planes > The 32 Crystal Classes |
The 32 crystal classes represent the 32 possible combinations of symmetry operations. Each crystal class will have crystal faces that uniquely define the symmetry of the class. These faces, or groups of faces are called crystal forms. Note that you are not expected to memorize the crystal classes, their names, or the symmetry associated with each class. You will, however, be expected to determine the symmetry content of crystal models, after which you can consult the tables in your textbook, lab handouts, or lecture notes. All testing on this material in the lab will be open book. In this lecture we will go over some of the crystal classes and their symmetry. I will not be able to cover all of the 32 classes. You will, however, see many of the 32 classes during your work in lab. I also want to point out that it is often not easy to draw a crystal of some classes where the symmetry can be represented without adding more symmetry or that can be easily seen in a two dimensional drawing. The table below shows the 32 crystal classes, their symmetry, Hermann-Mauguin symbol, and class name. Note that the 32 crystal classes are divided into 6 crystal systems.
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| Crystal System | Crystal Class | Symmetry | Name of Class |
| Triclinic | 1 | none | Pedial |
| i | Pinacoidal | ||
| Monoclinic | 2 | 1A2 | Sphenoidal |
| m | 1m | Domatic | |
| 2/m | i, 1A2, 1m | Prismatic | |
| Orthorhombic | 222 | 3A2 | Rhombic-disphenoidal |
| mm2 (2mm) | 1A2, 2m | Rhombic-pyramidal | |
| 2/m2/m2/m | i, 3A2, 3m | Rhombic-dipyramidal | |
| Tetragonal | 4 | 1A4 | Tetragonal- Pyramidal |
| Tetragonal-disphenoidal | |||
| 4/m | i, 1A4, 1m | Tetragonal-dipyramidal | |
| 422 | 1A4, 4A2 | Tetragonal-trapezohedral | |
| 4mm | 1A4, 4m | Ditetragonal-pyramidal | |
| 1 |
Tetragonal-scalenohedral | ||
| 4/m2/m2/m | i, 1 |
Ditetragonal-dipyramidal | |
| Hexagonal | 3 | 1A3 | Trigonal-pyramidal |
| 1 |
Rhombohedral | ||
| 32 | 1A3, 3A2 | Trigonal-trapezohedral | |
| 3m | 1A3, 3m | Ditrigonal-pyramidal | |
| 1 |
Hexagonal-scalenohedral | ||
| 6 | 1A6 | Hexagonal-pyramidal | |
| 1 |
Trigonal-dipyramidal | ||
| 6/m | i, 1A6, 1m | Hexagonal-dipyramidal | |
| 622 | 1A6, 6A2 | Hexagonal-trapezohedral | |
| 6mm | 1A6, 6m | Dihexagonal-pyramidal | |
| 1 |
Ditrigonal-dipyramidal | ||
| 6/m2/m2/m | i, 1A6, 6A2, 7m | Dihexagonal-dipyramidal | |
| Isometric | 23 | 3A2, 4A3 | Tetaroidal |
| 2/m |
3A2, 3m, 4 |
Diploidal | |
| 432 | 3A4, 4A3, 6A2 | Gyroidal | |
| 3 |
Hextetrahedral | ||
| 4/m |
3A4, 4 |
Hexoctahedral |
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Characterized by only 1-fold or 1-fold rotoinversion axis
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| Monoclinic System
Characterized by having only mirror plane(s) or a single 2-fold axis. |
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The most common minerals that occur in the prismatic class are the micas (biotite and muscovite), azurite, chlorite, clinopyroxenes, epidote, gypsum, malachite, kaolinite, orthoclase, and talc. |
| Orthorhombic System
Characterized by having only two fold
axes or a 2-fold axis and 2 mirror planes. |
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| Tetragonal System
Characterized by a single 4-fold or 4-fold rotoinversion axis. |
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| Note that I will not have time in lecture to cover the rest of the 32 crystal classes, that is those belonging to the hexagonal and isometric systems. These are difficult to draw, and are best left for the student to study using the textbook, pages 82-100, and the crystal models in lab. |
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